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Detection of the penetration of small molecules through polymers

✍ Scribed by Stanley E. Wentworth; Rosemary Goydan


Publisher
Wiley (John Wiley & Sons)
Year
1986
Tongue
English
Weight
214 KB
Volume
24
Category
Article
ISSN
0887-6258

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πŸ“œ SIMILAR VOLUMES


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The use of hybrid organic-inorganic materials in gas separation is a topic of great interest. One recent example is the observed increase in separation performance of polymers upon confinement in a mesoporous medium [M. Moaddeb, W.J. Koros, Journal of Membrane Science 125 (1997) 143-163]. In this pa

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The diffusion of fairly small organic molecules in polymers above their glass transitions is normally governed by Fick's law but with diffusion coetficients that are strongly, almost exponentially, increasing functions of penetrant concentration. Attempts to develop a comprehensive and quantitative

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Small molecules in glassy polymers are considered to occupy sites with a distribution of free energies of dissolution. Then their diffusivity depends on concentration and temperature in the same way as it has been derived for hydrogen atoms in metallic glasses. For hydrogen it was shown that the tra

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