๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

On the overhauser mechanism of chemically induced nuclear polarization as suggested by Adrian

โœ Scribed by G.L. Closs

Book ID
103014843
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
242 KB
Volume
32
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

The recently proposed Overhauser mechanism of nuclear polarization for certain types of reaction is compared with the conventional radical pair mechanism. It is concluded that both mechanisms willwork in these reactions if the Lifetimes of the free radicals are of the same order of magnitude or longer than the nuclear Tr .

๐Ÿ“œ SIMILAR VOLUMES

A possible overhauser mechanism for 19F
A possible overhauser mechanism for 19F nuclear spin polarization in the reaction of fluorobenzyl halides with sodium naphthalene
โœ F.J. Adrian ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 325 KB

It is proposed that the high field IgF nuclear spin polarization observed in fhe producr of the reaction of tluorobenzyl halides with sodium naphthalene is not due to the usual radical pair mechanism, but rather to a build up of electron spin polarization in the intermediate benzyl radical combined