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On the origin of the diastereoselectivity observed in cycloadditions of chiral acyl-nitroso compounds

✍ Scribed by Andrew Miller; Garry Procter

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
144 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

Suing

: Molecular ntechanics calculations support the models advanced to account for the diastereoselecdvity observed in cycloadditions to chirai acyl-nitroso compounds.

πŸ“œ SIMILAR VOLUMES

On the origin of Ο€-facial diastereoselec
On the origin of Ο€-facial diastereoselectivity in nucleophilic additions to chiral carbonyl compounds. 1. Rotational profiles of propionaldehyde 1, chloroacetaldehyde 2, and 2-chloropropionaldehyde 3.
✍ G Frenking; K.F KΓΆhler; M.T Reetz πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 757 KB

## SummarV : The conformational profiles for rotation around the C-C(=O) bond a and the energy minimum conformations are calculated for propionaldehyde 1, chloroacetaldehyde 2, MP2/6-3lG(d)//HF/6\_3lG(d). and 2-chloropropionaldehyde 3 at a function of a for 1, 2, The energy level of the LUMO is ca