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On the origin of satellite peaks in the high energy photoelectron spectra of some transition metal carbonyls

✍ Scribed by M. Barber; J.A. Connor; I.H. Hillier

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
236 KB
Volume
9
Category
Article
ISSN
0009-2614

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✦ Synopsis

Saieflite pea& in the high energy photoelectron spectra of a number of transition m&x& are ropo*d, and their origin ts suggested DS arising from the poor description of the ground states of t&Se molecules in the Hartree-Fock limit.

In this work we describe measurements, obtained on an AEI ES100 photoelectron sprectrometer of the high energy photoelectron spectra of a number of transition metal carbonyls. Ali spectra were obtained on solid samples condensed from the vapour at liquid nitrogen temperature. In fig. 1 WE show the spectra in the region of the ionization of carbon and oxygen Is electrons for Cr(C0) . In addition to the peaks

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