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On the nature of the lowest excited states of styrene: Calculation of the resonance Raman spectrum and pre-resonance profiles

โœ Scribed by G. Marconi


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
383 KB
Volume
14
Category
Article
ISSN
0377-0486

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โœฆ Synopsis


Abstract

The nature of the lowโ€lying excited single states of styrene has been investigated through calculation of the resonance Raman spectrum and preโ€resonance Raman profiles of the three modes of C๏ฃพC stretching nature. A reasonable agreement with experiment is found and an analysis of the main contributions to the intensity is provided in terms of vibronic matrix elements. The possibility of destructive interference of diagonal and offโ€diagonal terms is analysed for the three modes examined.


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