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On the n-.pi.* blue shift accompanying solvation

โœ Scribed by Karelson, Mati; Zerner, Michael C.


Book ID
126936447
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
280 KB
Volume
112
Category
Article
ISSN
0002-7863

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Solvation effects on the tautomerization
โœ Allan D. Headley; Binita Patel; Eric T. Cheung ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 185 KB

The effects that solvents have on the tautomerization of N,N-dimethylvaline were analyzed using a linear solvation energy relationship (LSER) approach. In solution, the population of the zwitterionic tautomer is dictated mainly by the nature of the medium. Acidic solvent molecules appear to be more