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Excited-state solvation vs. ground-state solvation in the n .fwdarw. .pi.* solvent blue shift of ketones and azo compounds

✍ Scribed by Haberfield, Paul; Lux, Michael S.; Rosen, Douglas

Book ID: 127069612
Publisher: American Chemical Society
Year: 1977
Tongue: English
Weight: 420 KB
Volume: 99
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00463a007

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Carbonyl n .far. .pi.* solvent blue shif

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Calorimetric studies in solution solvent effect on the carbonyl n → π# transition in relation with solvation of the ground and excited states

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TIP= relat.ivo salvation of the ground and the excited states corresponding to the n -L R\* W transition of carbonyl chromophores is determined, for a serie of solvents, on the basis of (11 the value of AE = hv, (2) the salvation enthaipy of the ground state determined by calorimetry, (3) the enthai