The oxidation of dissolved metal in acidic cryolite melts has been studied at tungsten, classy carbon and graphite electrodes using the techniques of cyclic voltammetry and chronopotentiometry. The reaction was found to be diffusion controlled and quasi-reversible with n = 2, suggesting that monoval
On the migration of dissolved aluminium in NaFAlF3Al2O3 melts
✍ Scribed by Jomar Thonstad; Ryszard Oblakowski
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 292 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
Aluminium dissolved in cryolite-alumina melts migrates in the direction of the positive pole by passage of current . By a modified moving boundary technique the dissolved metal was found to separate into two zones with different mobilities . For the cryolite composition at 11100°C the apparent mobilities were appros 21 x 10 -i and 3 x 10 -°ctaa -/V cm -' . The mobilities increased strongly with increasing temperature and increasing NaF/AIF 5 ratio .
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Abstractaxygen overvoltage on sintered anodes made of SnO, +2 wt % SbzOs + 2 wt% CuO was measured in 2.7 NaF-AIF,-Al,O,(sat) melts at 1000 "C. Prior to use the sintered elwtrodes were dipped into solutions containing doping agents. Doping with Ru, Fe and Cr showed a marked electrocatalytic efTect. R
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