On the mechanism of the thermal N-nitropyrazole rearrangement. Evidence for a [1,5] sigmatropic nitro migration
β Scribed by Janssen, Joseph W. A. M.; Habraken, Clarisse L.; Louw, Robert.
- Book ID
- 120082950
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 718 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
We wish to report direct evidence for a homolytic scission-recombination mechanism in the thermal eMeisenheimer" rearrangement' of the title compound, I, to the hydroxylamine, II (equation I). This mechanism W&B apparently first proposed by Schgllkopf,3 who adduced threefold
## Abstract The sequential rearrangement reaction mechanism of the 2βallylβ2,4,5βhexatrienaldehyde has been studied at the unrestricted Becke threeβparameter hybrid functional combined with LeeβYangβParr correlation functional (UB3LYP)/6β31G\*\*, Complete Active Space SelfβConsistent Field (CAS (8,