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On the Mechanism of the Organocatalytic Asymmetric Epoxidation of α,β-Unsaturated Aldehydes

✍ Scribed by Davis, Rebecca L.; Jensen, Kim L.; Gschwend, Björn; Jørgensen, Karl Anker


Book ID
123618630
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
319 KB
Volume
20
Category
Article
ISSN
0947-6539

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A novel organocatalytic highly enantioselective nitrocyclopropanation reaction of a,b-unsaturated aldehydes is presented. The 1-nitro-2-formylcyclopropane derivatives synthesized from this catalytic transformation were converted to the corresponding b-nitromethyl-acid esters, which are excellent pre