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Asymmetric Organocatalytic β-Hydroxylation of α,β-Unsaturated Aldehydes

✍ Scribed by Bertelsen, Søren; Dinér, Peter; Johansen, Rasmus Lyng; Jørgensen, Karl Anker

Book ID
120474070
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
73 KB
Volume
129
Category
Article
ISSN
0002-7863

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A novel organocatalytic highly enantioselective nitrocyclopropanation reaction of a,b-unsaturated aldehydes is presented. The 1-nitro-2-formylcyclopropane derivatives synthesized from this catalytic transformation were converted to the corresponding b-nitromethyl-acid esters, which are excellent pre