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On the Mechanism of the Isotopic Exchange of Tritium with Methane

✍ Scribed by Wexler, S.


Book ID
127031307
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
841 KB
Volume
85
Category
Article
ISSN
0002-7863

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Mechanism of isotope exchange reaction b
✍ W. C. Gardiner JR.; J. M. Herrmann; W. G. Mallard; J. H. Owen πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 636 KB

The rate of CHI disappearance in a shock-heated CHI: Dz: Ar = 9.70: 9.86: 80.44 mixture was monitored by coincidence absorption of the 2948 cm-I He-Ne laser line over the shockfront temperature range of 1900-2300K. Comparison with CHr pyrolysis results by means of computer simulations suggested that