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On the Mechanism of the Formation of Rearrangement Products in the Addition of Arenesulfenyl Chloride and 4-Phenyl-4H-1,2,4-triazole-3,5-dione to Benzonorbornadienes

โœ Scribed by Adam, Waldemar ;Carballeira, Nestor ;Scheutzow, Dieter ;Peters, Karl ;Peters, Eva-Maria ;Schnering, Hans Georg Von


Publisher
Wiley (John Wiley & Sons)
Year
1984
Tongue
English
Weight
753 KB
Volume
117
Category
Article
ISSN
0009-2940

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Unusual Rearrangement Products in the Cy
โœ Adam, Waldemar ;Lucchini, Vittorio ;Pasquato, Lucia ;Peters, Eva-Maria ;Peters, ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 577 KB

Cycloaddition of PTAD to 7-methylenenorbornene (1 a) afforded the rearrangement urazole 2a, but not with 7-(pheny1methylene)norbornene (1 b) and 7-(chloromethylene)norbornene (lc). Instead, besides the [2 + 23 cycloadducts 3b and 3c, respectively, l b gave the double [4 + 23 adduct 4b and l c the no