On the mechanism of the electrochemical reduction of TcO4−1ion on platinum cathode in sulphuric acid solutions
✍ Scribed by V. I. Spitsyn; A. F. Kuzina; A. A. Oblova; M. I. Glinkina; L. I. Stepovaya
- Book ID
- 112764643
- Publisher
- Springer
- Year
- 1976
- Tongue
- English
- Weight
- 206 KB
- Volume
- 30
- Category
- Article
- ISSN
- 1588-2780
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The cathodic potential-decay process on platinum electrodes in oleums has been investigated by means of a rotating disk. The non-steady parameters are compared with those already reported under steady-state conditions, Both results are discussed in terms of a general reaction mechanism comprising va
A~traet--CO~ reacts in acid solutions with chemisorbed hydrogen on platinum in the potential range of Eh = 0-250 mV to form a chemisorption product of reduced COs (perhaps CO). The rate of reduction on bright platinum at room temperature is very slow, taking more than 2 min at Eh = 0 for the total
Two reversible wavesare observed for the reduction of Ru(IV) on platinum electrodes. Each wave is the sum of two one-electron steps according to: 1st wllve Ru,(OH):: (IV)-Ru4(0H)$ (3,75)=Ru,(OH):+ (3.5) 2nd wave /wv-l Ru,(OH);+ (3,S)=Ru,(OH);+ (3.25)= Ru+(OH):+ (III) k, 4 stable Ru(II1) Potentials (