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On the mechanism of the acyl group migration in glycerol derivatives

✍ Scribed by P. E. Verkade

Book ID
104587192
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
133 KB
Volume
85
Category
Article
ISSN
0165-0513

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📜 SIMILAR VOLUMES

Migration of an acyl group in glycerol d
Migration of an acyl group in glycerol derivatives: IV. Migration of an acyl group upon boiling of glycerol derivatives with a mixture of acetic anhydride and acetic acid
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## Abstract Boiling of diphenyl distearoylglycerol‐α‐phosphate, diphenyl distearoylglycerol‐βT‐phosphate, distearoyl‐α‐methanesulphonylglycerol, and distearoyl‐βT‐(__p__‐toluenesulphonyl)glycerol with a mixture of acetic anhydride and acetic acid (1:4) gives a mixture of distearoyl‐α‐acetylglycerol

Migration of an Acyl group in glycerol d
Migration of an Acyl group in glycerol derivatives: III. An investigation of Fischer's method for the preparation of αγ-diglycerides
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## Abstract Heating of a monoacid diacylglycerol‐α‐iodohydrin or diacylglycerol‐β‐iodohydrin with silver nitrite or silver nitrate in a mixture of alcohol and water leads to an (equilibrium) mixture of the corresponding αβ‐and αγ‐diglycerides. Preparation of a monoacid αγ‐diglyceride in a good yiel

Migration of an acyl group in glycerol d
Migration of an acyl group in glycerol derivatives: II. Transformation of diacylglycerol-β-iodohydrins into diphenyl diacylglycerol-α-phosphates
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## Abstract The action of silver diphenyl phosphate on a diacylglycerol‐α‐iodohydrin or the isomeric diacylglycerol‐β‐iodohydrin in benzene as medium gives the diphenyl diacylglycerol‐α‐phosphate in practically equal and very satisfactory yields. In the latter case therefore a migration of an acyl