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Migration of an acyl group in glycerol derivatives: IV. Migration of an acyl group upon boiling of glycerol derivatives with a mixture of acetic anhydride and acetic acid

✍ Scribed by M. A. Hoefnagel; A. van Veen; P. E. Verkade

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
229 KB
Volume
81
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Boiling of diphenyl distearoylglycerol‐α‐phosphate, diphenyl distearoylglycerol‐βT‐phosphate, distearoyl‐α‐methanesulphonylglycerol, and distearoyl‐βT‐(p‐toluenesulphonyl)glycerol with a mixture of acetic anhydride and acetic acid (1:4) gives a mixture of distearoyl‐α‐acetylglycerol and distearoyl‐βT‐acetylglycerol in the proportion of about 9:1. An explanation of these and similar reactions is offered.

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