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On the mechanism of photoinduced addition of acetonitrile to phosphonium–iodonium ylides

✍ Scribed by Tatiana D. Nekipelova; Vladimir A. Kuzmin; Elena D. Matveeva; Rolf Gleiter; Nikolay S. Zefirov

Book ID
112175596
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
902 KB
Volume
26
Category
Article
ISSN
0894-3230

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Addition of NaW to RC=\_CfPh\*OTs results in novel alkylidenecarbene-iodonium ylides. 5, R(N )C-C=IPh. that ay either protonatlon, ylide transfer or insertion of the derived carbene K(N3)&: give unique functionalized vinyl azides. Despite the importance of ylidet, I. in carbene chem1stry.I until rec