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Kinetics and Mechanism of the Addition of Benzylamines to Benzylidenemalononitriles in Acetonitrile

✍ Scribed by Oh, Hyuck Keun; Yang, Jin Hee; Lee, Hai Whang; Lee, Ikchoon

Book ID
121354722
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
91 KB
Volume
65
Category
Article
ISSN
0022-3263

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The kinetics of addition of a number of ortho-, meta-, and para-substituted benzylamines to benzylidenemalononitrile (BMN) in acetonitrile have been studied. The reaction is first-order with respect to BMN. The order with respect to the amine is more than one. It has been shown that the reaction fol