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On the Mechanism of Oxidation. I. A New Type of Peroxide Rearrangement Catalyzed by Acid

✍ Scribed by Witkop, Bernhard; Patrick, James B.

Book ID
127104260
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
585 KB
Volume
73
Category
Article
ISSN
0002-7863

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Semiempirical calculations show that the intermediate formed by reaction between peroxydisulfate anion and the phenolate ion (the Elbs oxidation) is the species resulting from reaction of the tautomeric carbanion rather than the one resulting from attack by the oxyanion. This is confirmed by synthes