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Density Functional Study on the Mechanism of the Vanadium-Catalyzed Oxidation of Sulfides by Hydrogen Peroxide

✍ Scribed by Balcells, David; Maseras, Feliu; Lledós, Agustí

Book ID
117989983
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
213 KB
Volume
68
Category
Article
ISSN
0022-3263

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## Abstract The kinetics of the oxidation of substituted phenyl methyl sulfides by hydrogen peroxide in borate/boric acid buffers were investigated as a function of pH, total peroxide concentration, and total boron concentration. Second‐order rate constants at 25 °C for the reaction of methyl 4‐nit