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Computational Rationalization of the Dependence of the Enantioselectivity on the Nature of the Catalyst in the Vanadium-Catalyzed Oxidation of Sulfides by Hydrogen Peroxide

✍ Scribed by Balcells, David; Maseras, Feliu; Ujaque, Gregori


Book ID
125481705
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
276 KB
Volume
127
Category
Article
ISSN
0002-7863

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Borate-Catalyzed Reactions of Hydrogen P
✍ D. Martin Davies; Michael E. Deary; Kieran Quill; Robert A. Smith πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 258 KB πŸ‘ 2 views

## Abstract The kinetics of the oxidation of substituted phenyl methyl sulfides by hydrogen peroxide in borate/boric acid buffers were investigated as a function of pH, total peroxide concentration, and total boron concentration. Second‐order rate constants at 25 °C for the reaction of methyl 4‐nit