𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the mechanism of ethylene and propylene insertion into metal-hydroxo bonds

✍ Scribed by Shumilo, O. N. ;Bulgakov, N. N. ;Likholobov, V. A.


Book ID
112683818
Publisher
Springer
Year
1983
Tongue
English
Weight
320 KB
Volume
22
Category
Article
ISSN
0133-1736

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Mechanism of metal-carbenoid insertion i
✍ Yannick Landais; Liliana Parra-Rapado; Denis Planchenault; ValΓ©ry Weber πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 286 KB

Kinetic investigations on the insertion of metal-carbenoid intermediates into the Si-H bond have been carried out. A kinetic isotope effect of 1.5 was found and the plot of log kx/krt vs cr for the reaction of arylsilanes with EDA, gave a straight line with p =-0.31. It was thus concluded that the i