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On the mechanism of diffusion and ionic transport in crystalline insoluble acid salts of tetravalent metals—II self diffusion of Na+ and K+ on microcrystals of Zr(NaPO4)2·3H2O and Zr(KPO4)2·3H2O

✍ Scribed by U. Constantino; L. Naszodi; L. Szirtes; L. Zsinka

Book ID
115975157
Publisher
Elsevier Science
Year
1978
Weight
344 KB
Volume
40
Category
Article
ISSN
0022-1902

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✍ A.M.Shams El Din; A.A.A. Gerges 📂 Article 📅 1964 🏛 Elsevier Science 🌐 English ⚖ 322 KB

The four acids NaH,PO,, Na2HPO,, NaPO3 and Na4P,.O7 were titrated potentiometricall), with NazO, in molten KNOs at 350°C. An oxygen electrode acted as indicator electrode, while a Ag/Ag(1) electode served as a suitable reference electrode. NaH2PO, neutralized in two steps, the second of which was id