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On the mechanism of cis-ligand insertion

✍ Scribed by P. Cossee


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
379 KB
Volume
85
Category
Article
ISSN
0165-0513

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Mechanism of metal-carbenoid insertion i
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Kinetic investigations on the insertion of metal-carbenoid intermediates into the Si-H bond have been carried out. A kinetic isotope effect of 1.5 was found and the plot of log kx/krt vs cr for the reaction of arylsilanes with EDA, gave a straight line with p =-0.31. It was thus concluded that the i