On the mechanism of anodic acetamidation
โ Scribed by V.D. Parker; B.E. Burgert
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 25 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The discovery2a3\*4 that large alkaues can be directly oxidized In acetouitrile at a platinum anode provides access to the anodic chemistry of a variety of 8lipbatic compouuds. In the present Investigation, we have oxidized several adanantyl compounds as an initial step in elucidating this chemistr
On tb basis of polarographic studies and preparative investigationa at controlled anode potentials lr2, we have previously postulated that anodie acetorylation of an organic substrate in acetic acid/acetate Ion proceeddi via an initial two-electron transfer from the substrate to the anode. The dlcat
## THE MECHANISM of anodic substitution reaction such as acetoxylation, cyanation etc of aromatic compounds has been widely elucidated.lA Reviews on the problem are available.6>s Eberson first systematically proposed that an organic substrate is anodically oxidized with a two-electron withdrawal