𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the mechanism derived from kinetic solvent effects of Grignard reactions with silanes

✍ Scribed by Ants Tuulmets; Dmitri Panov; Meeri Sassian

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
63 KB
Volume
44
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

In this communication we present the results of initial kinetic studies in which we have established that alkoxysilanes and chlorosilanes react with Grignard reagents in entirely different ways. The Grignard reaction with alkoxysilanes consists of replacement of a donor molecule at the magnesium centre by silane, followed by a subsequent rearrangement of the complex to the products. Chlorosilanes react without solvent molecule replacement.

πŸ“œ SIMILAR VOLUMES

Substituent effects on the reaction of t
Substituent effects on the reaction of trityl chlorides with Grignard reagents
✍ Ryan E. Oyler; Benjamin E. Ketz; Timothy E. Glass πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 77 KB

The result of the substitution of trityl chlorides with Grignard reagents was found to be highly dependent on the solvent and the nature of the substituents on the trityl group. In THF, electron donating substituents were found to give high yields of Grignard addition while electron withdrawing subs