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On the magnetic non-equivalence of methylene protons in some propane derivatives, and its variation with solvent and temperature

✍ Scribed by Y.A. Shahab; M.S. Saeed

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
308 KB
Volume
40
Category
Article
ISSN
0022-2860

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Conformationally dependent influence of
Conformationally dependent influence of 3-substituents on the observable magnetic non-equivalence of benzylic methylene protons in N-benzylpiperidines
✍ M. A. Iorio; A. F. Casy 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 388 KB

## Abstract Examples are given of the conformationally dependent influence of 3‐substituents (methyl, __n__‐propyl, allyl, aryl, hydroxy and acyloxy) on the magnetic non‐equivalence of the benzylic methylene protons (N__CH__~2~Ph) of __N__‐benzylpiperidine as observable by ^1^H NMR. The results, to