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On the Influence of the Bite Angle on the Allylic Alkylation of (E) and (Z) Substrates: Loss and Retention of Double Bond Stereochemistry

✍ Scribed by Richard J. van Haaren; Gino P. F. van Strijdonck; Henk Oevering; Joost N. H. Reek; Paul C. J. Kamer; Piet W. N. M. van Leeuwen

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
262 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The Effect of the Bite Angle of Diphosph
The Effect of the Bite Angle of Diphosphane Ligands on Activity and Selectivity in Palladium-Catalyzed Allylic Alkylation
✍ Mirko Kranenburg; Paul C. J. Kamer; Piet W. N. M. van Leeuwen 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB 👁 1 views

The effect of the natural bite angle (β n ) of diphosphane li-angle of the ligand becomes larger. This results in an increasing selectivity at larger bite angles, but at very large gands on catalyst selectivity and activity in the palladiumcatalyzed allylic alkylation was investigated. The selectivi