On the influence of hydroxyl radicals on the kinetics of the combustion reaction of carbon monoxide
β Scribed by P. Laffitte; F. Cusin; H. James
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- English
- Weight
- 394 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0010-2180
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Replacement of N 2 by CO in H 2 + 02 + N 2 mixtures undergoing slow reaction at 500Β°C causes a marked increase in the reaction rate and a decrease in the induction period, expressed as the time to half maximum rate. A detailed interpretation using a computer treatment gives k24/klo 1/2 = 0.42 Β± 0.03
The kinetics of the reaction CH,+OH (+M)dCH,OH (+M) was studied at room temperature by pulse radiolysis of SF,/ CHJH# mixtures. The methyl radical decay was followed by monitoring the UV absorption signals at 216.4 nm. A pressure dependence of k, was observed with values ranging from (5.8 kO.3) x 10
## Abstract The presence of small concentrations of inhibitors (CCl4, Cl2 and HCL) in the air passing into a bed of burning coke is found to increase the CO content of the combustion gases at the expense of the CO2. With sufficient inhibitor (> 2.0% CCL4) the effect amounts to almost complete suppr