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On the impedance of galvanic cells: XXI. Analysis of the electrode impedance in the case of a non-reversible electrode reaction with specific adsorption of the electroactive species; appl

โœ Scribed by M. Sluyters-Rehbach; B. Timmer; J.H. Sluyters


Publisher
Elsevier Science
Year
1967
Weight
837 KB
Volume
15
Category
Article
ISSN
0022-0728

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On the impedance of galvanic cellsโ€”XVI:
โœ M. Sluyters-Rehbach; J.H. Sluyters ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 604 KB

The discharge of K+ ions at the dropping mercury electrode (dme) in 1 M KC1 solution at 25ยฐC has been studied by means of analysis of the electrode impedance at different frequencies, using the complex plane method. It is shown that the electrode reaction is almost entirely diffusioncontrolled, but