On the impedance of electrodes with rough interfaces
β Scribed by R. de Levie
- Book ID
- 107794432
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 567 KB
- Volume
- 261
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
The impact of the electrode morphology on the overall impedance in liquid and solid electrochemistry is discussed for two examples: for an electrode with small surface roughness and for an electrode exhibiting deep, equidistant pores. The impedance is calculated numerically using the finite element
Recent theoretical results reported by Nyikos and Pajkossy (N-P) on fractal electrolyte/blocking electrode interfaces have been tested with numerical calculations. It is shown that (I) interfaces having electrolyte-metal boundaries in form of a generalized Koch curve do not have a constant-phase-ang