On the diffusional impedance of microdisc electrodes
β Scribed by L.M. Abrantes; M. Fleischmann; L.M. Peter; S. Pons; B.R. Scharifker
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 328 KB
- Volume
- 256
- Category
- Article
- ISSN
- 0022-0728
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## Abstract A simple generic model to predict the influence of electrode porosity on the cyclic voltammetric response of an electrode is presented. The conditions under which deviation from the behavior of a perfectly flat, planar electrode can be expected are predicted. The scope for misinterpreta
Impedance data of the Ag/Ag+ electrode at equilibrium potential are interpreted on the basis of Lorenz et al.3 model of partially active electrode surface. Linear and lateral diffusion controlled the faradaic process on active parts, in parallel with linear and lateral diffusion controlled adsorptio