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On the general theory of polymer absorption at a surface

✍ Scribed by Hoeve, C. A. J.


Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
313 KB
Volume
30
Category
Article
ISSN
0449-2994

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✦ Synopsis


Abstract

Previous theoretical work dealt with polymer adsorption in which the adsorbed segments (trains) interact in the surface layer only. In this work the treatment is extended to Include also interaction between the loops dangling in solution. Fortunately, the excluded volume effects for adsorbed polymer chains are found to be small. Therefore an approximate treatment is possible that leads to equations that govern polymer chains under a wide variety of conditions.


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## Abstract A unified theory of field‐, thermo‐, and photoemission from metal surface is considered, and the general quantum‐mechanical methods for the investigation of the threshold phenomena are applied. As result the corresponding final expressions are obtained in such a form that it is possible