A detailed investigation of the ionization of NO by photoelectron spectroscopy at three different wavelengths leads to a first ionization ootential of8.8 eV. Vibrational structure is observed and it is shown that the measured 2016 cm-1 ionic frequency. corresponding to ~3 or (~1 f ~2). is indicative
โฆ LIBER โฆ
On the first ionization potentials of nitrogen dioxide and nitric oxide
โ Scribed by C.R. Brundle
- Book ID
- 107731418
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 510 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-2614
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By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio