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The adsorption of nitric oxide and nitrogen dioxide on polycrystalline platinum

✍ Scribed by D.T. Wickham; B.A. Banse; B.E. Koel

Publisher: Elsevier Science
Year: 1989
Weight: 51 KB
Volume: 223
Category: Article
ISSN: 0167-2584
DOI: 10.1016/0167-2584(89)90667-1

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By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio