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On the exchange current density of the Fe(III)/Fe(II) oxalate electrode reaction at a mercury electrode

โœ Scribed by J. H. Sluyters; M. Sluyters-Rehbach; M. D. Wijnen; J. H. M. Rek


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
67 KB
Volume
85
Category
Article
ISSN
0165-0513

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The redox system Fe(III)/Fe(II) oxalate
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The dissociation equilibria of the complex ions present in a solution of Fe(III) and/or Fe(H) oxalate systems depend upon the pH, since H&,0, is a weak acid. Equilibrium diagrams have been drawn from the best information available about stability constants of these systems. Absorption spectra sugges

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The electrode reactions of the Fe(II)-NCS system occurring at mercury electrodes have been studied by using cyclic voltammetry and large scale electrolysis. The elatroreduction of Fe(H) in that system occurs with a fast transfer of the first electron. The resulting intermediate complex of iron(I) is