A series of S-alkyl thioformates, HC(O)SR, has been synthesized by formylation of alkane thiols and their behaviour upon electron impact has been investigated by using tandem mass spectrometry methodologies. When R > CH 3 , a prominent loss of a SH β’ radical is observed in the ion source as well as
β¦ LIBER β¦
On the evidence for the generation of a ferrocenylsilicenium ion
β Scribed by Paul Bickart; Francisco M. Llort; Kurt Mislow
- Book ID
- 108347176
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 133 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0022-328X
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## Abstract In __m__βnitrobenzaldoxime a strongly enhanced loss of OHβ is observed as compared with the pβnitro compound. Evidence is presented for a fragmentation mechanism involving the formation of a cyclohexadieneβtype intermediate ion formed by a rearrangement of the hydroxyl hydrogen to the p