✦ LIBER ✦

On the ESR spectra of matrix-stabilized hydronium radicals H3O and D3O

✍ Scribed by N.D. Chyvylkin; G.M. Zhidomirov

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 120 KB
Volume: 14
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)87143-4

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✦ Synopsis

The results of INDO calculations do not support the discovery of the I-i30 free radical_ Recently Martin and Swift [I ] came to the conelusion that they had clearly demonstrated "the first direct and unequivocal evidence for the hydronium radical" H,O. Their H30 spectrum is characteristic of a free radical that has axial symmetry with three equivalent hydrogen atoms. x similar spectrum could arise from such free radicals as BHF, CH,, NH;,

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