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Hypervalent radicals; the generation of CH3O(H)CH3, CH3O(H)C2H5 and their O-(D) analogues by neutralization of the corresponding cations

✍ Scribed by J. L. Holmes; M. Sirois

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
158 KB
Volume
25
Category
Article
ISSN
1076-5174

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✦ Synopsis

OMS Letters

Dear Sir

Hypervalent Radicals ; the Generation of CH,O(H)CH, ,

CH,O(H)C,H, and Their O-(D) Analogues by Neutralization of the Corresponding Cations

πŸ“œ SIMILAR VOLUMES

UV absorption spectra of HO2, CH3O2, C2H
UV absorption spectra of HO2, CH3O2, C2H5O2, and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3
✍ Ole J. Nielsen; Matthew S. Johnson; Timothy J. Wallington; Lene K. Christensen; πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 314 KB

## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to Οƒ(CH~3~O~2~)~240 nm~ = (4.24 Β± 0.27) Γ— 10^βˆ’18^, the following absorption cross sections were determined: Οƒ(HO~2~)~240 nm~ = 1.29 Β± 0