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On the enzymic mechanism of acetoacetate synthesis

โœ Scribed by Joseph R. Stern; Glen E. Miller


Book ID
115788413
Publisher
Elsevier Science
Year
1959
Weight
129 KB
Volume
35
Category
Article
ISSN
0006-3002

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The mechanism of acetoacetate coupling i
โœ Brian A. McGaw; Jack G. Woolley ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 182 KB

Sodium[3-14C]-and [4-14C]-acetoacetate were wick fed to 3-month-old Nicandra physaZoides plants. The hygrine was isolated and by degradation it was shown that acetoacetate is a precursor. It was also shown that the C(2) carbon is the reactive site in its condensation with the N-methyl-A'-pyrrolinium