๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

On the effect of deuteration on non-radiative processes in large molecules

โœ Scribed by B. Sharf; R. Silbey


Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
248 KB
Volume
5
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis


It is sho\n that the non-radiative decay of the fluorescing state CIE Large polyatomic molecules might exhibit nn inverse or retarded deuteration effect.


๐Ÿ“œ SIMILAR VOLUMES


On the temperature dependence of non-rad
โœ E.R. Pantke; H. Labhart ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 440 KB

It is shown that the fluorescence quantum yield depends on temperature rather than on the viscosity of the solvent. The intersystem crossing rate can IX described ;1s a sum of a temperature independent and a temperature dependent term. I;or most of the molecules investigated in this paper the latter

Effect of electronic correlations on rad
โœ E. Hiroike ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 298 KB

The effects of the electronic correktions on the radiative transition nutris elements are investigated theoretically. The calculation shows that the effective electronic configurations are drastically reduced by utilizing the modified H-F operator.

The deuterium effect on the triplet radi
โœ Philip M. Johnson; Mario C. Studer ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 435 KB

of.reIative quantum yields of pkosphorescene have been made for naphthalene versus perdeuteranaphthalenc and for toluene versus perdeutcrotoluene, all contained in argon crystds at 20ยฐK. In combination with tripIet lifetime measurements these quantum yield ratios give the ratios of radiative tripfet

On the theory of non-adiabatic effects i
โœ E. Deumens; L. Lathouwers; P. Van Leuven ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 354 KB

It is shown that the generator coordinate approximation introduces non-adiabatic effects of the correct sign (ener,g lowerinrz) and size (Born-Oppenheimer analysis)\_ The theoretical expression applied to diatomic molecules qualitatively explains the observed trends of non-adiabatic energy correctio