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On the Diels–Alder reactions and the Lewis acid induced rearrangements of 6-fumaryl 1,3,8-nonatrienes

✍ Scribed by Paul A. Clarke; Rebecca L. Davie; Simon Peace

Book ID
104250800
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
76 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

C5 position by a vinyl group were found to undergo competing tandem sigmatropic rearrangement/Diels-Alder cyclisation when heated under standard Diels-Alder cyclisation conditions. This rearrangement became the exclusive pathway when the reactions were performed in the presence of a Lewis acid.

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