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On the deprotonation of the cation radicals of substituted ethylenes. A heterolytic or homolytic process?

✍ Scribed by Santiago Camanyes; JoséM. Lluch; Juan Bertrán


Book ID
107943017
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
728 KB
Volume
204
Category
Article
ISSN
0301-0104

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Evidence for a stereoelectronic inhibition of deprotonation of versus electron-transfer routes in the biomimetic oxidative N-dealkylation of tertiary amines: the electron-transfer route the radical cation of N-benzylpiperidine is presented. This stereoelectronic effect, which is due to the cyclic st