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On the dependence of the electron band maximum on the solvent reorganization energy

✍ Scribed by Edward L. Mertz


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
376 KB
Volume
262
Category
Article
ISSN
0009-2614

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The photoelectron emission method was used to determine the reorganization free energy of nuclear coordinates in one-electron oxidation reactions. The experimental results for eight ferrous complexes, some of which have large organic ligands, in aqueous solution are in excellent agreement with the t