ON THE COURSE OF THE ADDITION OF MALONIC ENOLATES TO α,β-UNSATURATED ESTERS
✍ Scribed by MICHAEL, ARTHUR
- Book ID
- 120245862
- Publisher
- American Chemical Society
- Year
- 1937
- Tongue
- English
- Weight
- 283 KB
- Volume
- 02
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The addition of&-nucleophiles to unsaturated substrates has recently drawn both theoretical1 and experimental attention. 2 In this report we present data pertaining to the addition ofd-nucleophiles to Cr,$ -unsaturated esters, in particular ethyl cinnamate. We 'lWe h ave also obtained oils having h
Preformed lithium enolates of ketones react with acyclic a,p-unsaturated ketones to give 1,5-diketones in good chemical yields. A strong correlation exists between enolate geometry and product stereochemistry; enolates having the z configuration provide anti addition products while E enolates usua