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On the condensation of ferrocene with ketones

โœ Scribed by T.A. Sokolinskaya; T.P. Vishnyakova; Ya.M. Paushkin; Ya.A. Popova


Book ID
118357868
Publisher
Elsevier Science
Year
1967
Weight
439 KB
Volume
9
Category
Article
ISSN
0032-3950

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Electrophilic condensation of pyrimidines with cyclic ketones was investigated. As nucleophiles,the degreeof ionizationof pyrimidinesin acidicmedia and the electrondensityon the C-5 determinedthe reactivity.An electron-richnitrogenat the 4-positionof cyclic ketonesfacilitatedthe reaction.This methcd