On the changes of rate constants and activation energies during catalytic reactions. Decomposition of NaOCl and H2O2
β Scribed by L. Kreja
- Publisher
- Springer Vienna
- Year
- 1996
- Tongue
- English
- Weight
- 367 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0026-9247
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π SIMILAR VOLUMES
The rate constants k,, k2 and t for the reactions of N( 'D) atoms with I-I>, HF, and 02, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 kO.8) x IO-'\*, (1.0\_+0.3) x lo-'" and (6.6 f 1.0) X lo-l2 cm3 s-l, respectively. Previous
The rate consorts of several H=O+ reactions have been measured as a function of relative kinetic energy in a ffow&ift tube The reactions were found to proceed in a variety of ways -charge transfer, proton transfer. and H-aom &strxtton and to have onl) moderate kinetic-energy dependences.