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On the CH3/CF3 substitution effect. The gas-phase structure of 1,1,1,3,3,3-hexafluoropropane

✍ Scribed by Hans-Georg Mack; Heinz Oberhammer; Martin Grosser; Marwan Dakkouri

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
440 KB
Volume
268
Category
Article
ISSN
0022-2860

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πŸ“œ SIMILAR VOLUMES

Substituent effects on the disproportion
Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. Part III: Reactions of CF3 + CF3CH2 CHCF3 and CF3 CH2CHCF3 + CF3CH2 CHCF3
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Disproportionationkombination rate constant ratios, kd/&[, for the reactive collision between CF3CH2CHX + CF, radicals and between CF3CH2CHX + CF3CH2CHX radicals have been measured for X = CF, The kd/k, = 0.066 -t 0 01 3 when H is transferred to the CF3 radical and 0 I25 ? 0.025 for H transfer to th

Substituent effects on the disproportion
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## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 Β± 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 Β± 0.03 when the H is removed from the CH~3~ position in the reaction with t