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On the C-9 configuration of veratramine and jervine

✍ Scribed by Denis M. Bailey; David P.G. Hamon; William S. Johnson

Book ID
104241866
Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
275 KB
Volume
4
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Revision of the configuration of veratra
Revision of the configuration of veratramine and jervine
✍ John W. Scott; Lois J. Durham; Hendrik A.P. deJongh; Urs Burckhardt; William S. πŸ“‚ Article πŸ“… 1967 πŸ› Elsevier Science 🌐 French βš– 305 KB

We present herewith proof that the configurations of veratramine and of jervine are correctly represented by formulas I and II, \* respectively, rather than by III and IV, as previously postulated (1). It follows that the configuration of verarine, which has been shown (2) to be 23\_deoxyveratramine

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The harmonic frequencies and infrared intensities of Cg, Cl1 and Cl3 have been calculated using SCF and complete active space SCF (CASSCF) methods. The ordering of the harmonic frequencies in CS is predicted wrongly unless at least the v HOMO and LUMO are included in the active space. Infrared inten