On the bonding and reactivity of CO2 on metal surfaces
β Scribed by H.-J. Freund; R.P. Messmer
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 56 KB
- Volume
- 172
- Category
- Article
- ISSN
- 0167-2584
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π SIMILAR VOLUMES
Density functional theory was used to investigate the chemical reactivity of oxygen vacancies on the MgO surface towards CO 2 , NO 2 and metal atoms. The oxygen vacancies induce changes in the electronic structure of the MgO compared to that of the regular surface. The most common surface defects ca
Electron spectroscopic studies clearly demonstrate that modification of the surfaces of Mn, Fe and Ni metals by chlorine significantly decreases the strength of interaction between the metal and adsorbed molecules such as CO and N2. This is in contrast to the effect of electropositive additives such
Ultraviofet photoekction spectra from Rh~(C0)16 and from CO adsorbed on a Pd(l11) single crystal surfzce evhtblt cIose slmllarities which become further evident from a comparison of vibrational and thermal properties. These results demonstrate the localized character of the chemisorption bond and ju